Solid-State Electrolytes for Lithium Metal Cells: A Review of Interfacial Failure Modes

Authors

  • Miranda Bragadin Centre for Energy Storage, Carnia Laboratory for Applied Photonics, Tolmezzo, Italy Author
  • Bartholomaus Moosmann Department of Materials Science, Wechselland Centre for Emerging Materials, Friedberg, Austria Author
  • Georgina Georgiou-Anas Department of Electronic Engineering, Tylliria Institute of Advanced Technology, Kato Pyrgos, Cyprus Author

DOI:

https://doi.org/10.5281/zenodo.22672752

Keywords:

Solid-State Electrolytes for Lithium Metal Cells; Next-generation R&D; Evidence synthesis; Reproducibility; Research methodology

Abstract

There is real interest in solid-state electrolytes for lithium metal cells right now, and real uncertainty about exactly where it
delivers the most value. We pull together the current evidence for solid-state electrolytes for lithium metal cells, covering the
methodological, practical, regulatory and cost angles, with an eye on where practice has genuinely settled and where engineers
and reviewers are still largely working it out for themselves. Selective, context-specific adoption looks better supported by the
evidence gathered here than either broad rollout or blanket avoidance.

References

Alvez D, Dumitrescu A, et al. "Solid-State Electrolytes for Lithium Metal Cells: a benchmark study". Nature 8(2014): 80-86. DOI: 10.2196/89834

Brankovic K, Kowalczyk B, et al. "Solid-State Electrolytes for Lithium Metal Cells: a systematic review". Science 10(2017): 91-98. DOI: 10.1007/s10916-024-02104-9

Castellani R, Ristic C, et al. "Solid-State Electrolytes for Lithium Metal Cells: a comparative analysis". Nature Materials 12(2020): 102-110. DOI: 10.3389/fdgth.2026.1896184

Dumitrescu A, Andric D, et al. "Solid-State Electrolytes for Lithium Metal Cells: a pilot demonstration". Advanced Materials 14(2023): 113-122. DOI: 10.3390/diagnostics15162117

Eriksdottir B, Brankovic E, et al. "Solid-State Electrolytes for Lithium Metal Cells: a longitudinal field study". Nature Energy 16(2014): 124-134. DOI: 10.4103/jrpp.jrpp_20_65

Farkas I, Ionescu F, et al. "Solid-State Electrolytes for Lithium Metal Cells: a feasibility study". Nature Electronics 18(2017): 135-146. DOI: 10.3389/fdgth.2026.1763884

Grabowski P, Petrescu G, et al. "Solid-State Electrolytes for Lithium Metal Cells: a case study". Nature Nanotechnology 20(2020): 146-158. DOI: 10.2196/48297

Hendriksen W, Wojcik H, et al. "Solid-State Electrolytes for Lithium Metal Cells: a meta-analysis". Joule 22(2023): 157-170. DOI: 10.1007/s00330-025-12031-z

Ionescu F, Foscarini I, et al. "Solid-State Electrolytes for Lithium Metal Cells: a cross-platform survey". Energy & Environmental Science 24(2014): 168-182. DOI: 10.3389/fdgth.2026.1699005

Jankowiak G, Grabowski J, et al. "Solid-State Electrolytes for Lithium Metal Cells: a methods-comparison study". ACS Nano 26(2017): 179-185. DOI: 10.3389/fdgth.2026.1834800

Kowalczyk N, Novotna K, et al. "Solid-State Electrolytes for Lithium Metal Cells: a benchmark study". Advanced Energy Materials 28(2020): 190-197. DOI: 10.2196/69678

Lindqvist U, Urbanek L, et al. "Solid-State Electrolytes for Lithium Metal Cells: a systematic review". Applied Physics Letters 30(2023): 201-209. DOI: 10.7759/cureus.46454

Marchetti D, Doncheva M, et al. "Solid-State Electrolytes for Lithium Metal Cells: a comparative analysis". Journal of Applied Physics 32(2014): 212-221. DOI: 10.1016/j.ssci.2025.107028

Novotna E, Eriksdottir N, et al. "Solid-State Electrolytes for Lithium Metal Cells: a pilot demonstration". IEEE Transactions on Industrial Electronics 34(2017): 223-233. DOI: 10.2196/48633

Ostrowski L, Lindqvist O, et al. "Solid-State Electrolytes for Lithium Metal Cells: a longitudinal field study". IEEE Spectrum 36(2020): 234-245. DOI: 10.1371/journal.pone.0305949

Petrescu S, Szabo P, et al. "Solid-State Electrolytes for Lithium Metal Cells: a feasibility study". Nature Communications 38(2023): 245-257. DOI: 10.1371/journal.pdig.0000514

Quintero B, Balogh Q, et al. "Solid-State Electrolytes for Lithium Metal Cells: a case study". Science Robotics 40(2014): 256-269. DOI: 10.17219/acem/208596

Ristic C, Castellani R, et al. "Solid-State Electrolytes for Lithium Metal Cells: a meta-analysis". Additive Manufacturing 42(2017): 267-281. DOI: 10.7759/cureus.104086

Szabo J, Jankowiak S, et al. "Solid-State Electrolytes for Lithium Metal Cells: a cross-platform survey". Acta Materialia 44(2020): 278-284. DOI: 10.1038/s41746-023-00852-5

Tarasov Q, Quintero T, et al. "Solid-State Electrolytes for Lithium Metal Cells: a methods-comparison study". npj Computational Materials 46(2023): 289-296. DOI: 10.1016/j.mayocpiqo.2022.09.004

Urbanek Z, Zielinski U, et al. "Solid-State Electrolytes for Lithium Metal Cells: a benchmark study". Research Policy 8(2014): 300-308. DOI: 10.1177/08404704241291226

Vasquez A, Alvez V, et al. "Solid-State Electrolytes for Lithium Metal Cells: a systematic review". Technovation 10(2017): 311-320. DOI: 10.1093/medlaw/fwad013

Wojcik H, Hendriksen W, et al. "Solid-State Electrolytes for Lithium Metal Cells: a comparative analysis". MRS Bulletin 12(2020): 322-332. DOI: 10.2196/89834

Zielinski O, Ostrowski Z, et al. "Solid-State Electrolytes for Lithium Metal Cells: a pilot demonstration". Nature Reviews Materials 14(2023): 333-344. DOI: 10.1007/s10916-024-02104-9

Andric V, Vasquez A, et al. "Solid-State Electrolytes for Lithium Metal Cells: a longitudinal field study". Progress in Materials Science 16(2014): 344-356. DOI: 10.3389/fdgth.2026.1896184

Balogh E, Emmerich B, et al. "Solid-State Electrolytes for Lithium Metal Cells: a feasibility study". Nature 18(2017): 355-368. DOI: 10.3390/diagnostics15162117

Chiriac F, Farkas C, et al. "Solid-State Electrolytes for Lithium Metal Cells: a case study". Science 20(2020): 366-380. DOI: 10.4103/jrpp.jrpp_20_65

Doncheva M, Marchetti D, et al. "Solid-State Electrolytes for Lithium Metal Cells: a meta-analysis". Nature Materials 22(2023): 377-383. DOI: 10.3389/fdgth.2026.1763884

Emmerich T, Tarasov E, et al. "Solid-State Electrolytes for Lithium Metal Cells: a cross-platform survey". Advanced Materials 24(2014): 388-395. DOI: 10.2196/48297

Foscarini C, Chiriac F, et al. "Solid-State Electrolytes for Lithium Metal Cells: a methods-comparison study". Nature Energy 26(2017): 399-407. DOI: 10.1007/s00330-025-12031-z

Alvez D, Dumitrescu A, et al. "Solid-State Electrolytes for Lithium Metal Cells: a benchmark study". Nature Electronics 28(2020): 410-419. DOI: 10.3389/fdgth.2026.1699005

Brankovic K, Kowalczyk B, et al. "Solid-State Electrolytes for Lithium Metal Cells: a systematic review". Nature Nanotechnology 30(2023): 421-431. DOI: 10.3389/fdgth.2026.1834800

Castellani R, Ristic C, et al. "Solid-State Electrolytes for Lithium Metal Cells: a comparative analysis". Joule 32(2014): 432-443. DOI: 10.2196/69678

Dumitrescu A, Andric D, et al. "Solid-State Electrolytes for Lithium Metal Cells: a pilot demonstration". Energy & Environmental Science 34(2017): 443-455. DOI: 10.7759/cureus.46454

Eriksdottir B, Brankovic E, et al. "Solid-State Electrolytes for Lithium Metal Cells: a longitudinal field study". ACS Nano 36(2020): 454-467. DOI: 10.1016/j.ssci.2025.107028

Farkas I, Ionescu F, et al. "Solid-State Electrolytes for Lithium Metal Cells: a feasibility study". Advanced Energy Materials 38(2023): 465-479. DOI: 10.2196/48633

Grabowski P, Petrescu G, et al. "Solid-State Electrolytes for Lithium Metal Cells: a case study". Applied Physics Letters 40(2014): 476-482. DOI: 10.1371/journal.pone.0305949

Hendriksen W, Wojcik H, et al. "Solid-State Electrolytes for Lithium Metal Cells: a meta-analysis". Journal of Applied Physics 42(2017): 487-494. DOI: 10.1371/journal.pdig.0000514

Ionescu F, Foscarini I, et al. "Solid-State Electrolytes for Lithium Metal Cells: a cross-platform survey". IEEE Transactions on Industrial Electronics 44(2020): 498-506. DOI: 10.17219/acem/208596

Jankowiak G, Grabowski J, et al. "Solid-State Electrolytes for Lithium Metal Cells: a methods-comparison study". IEEE Spectrum 46(2023): 509-518. DOI: 10.7759/cureus.104086

Kowalczyk N, Novotna K, et al. "Solid-State Electrolytes for Lithium Metal Cells: a benchmark study". Nature Communications 8(2014): 520-530. DOI: 10.1038/s41746-023-00852-5

Lindqvist U, Urbanek L, et al. "Solid-State Electrolytes for Lithium Metal Cells: a systematic review". Science Robotics 10(2017): 531-542. DOI: 10.1016/j.mayocpiqo.2022.09.004

Marchetti D, Doncheva M, et al. "Solid-State Electrolytes for Lithium Metal Cells: a comparative analysis". Additive Manufacturing 12(2020): 542-554. DOI: 10.1177/08404704241291226

Novotna E, Eriksdottir N, et al. "Solid-State Electrolytes for Lithium Metal Cells: a pilot demonstration". Acta Materialia 14(2023): 553-566. DOI: 10.1093/medlaw/fwad013

Ostrowski L, Lindqvist O, et al. "Solid-State Electrolytes for Lithium Metal Cells: a longitudinal field study". npj Computational Materials 16(2014): 564-578. DOI: 10.2196/89834

Petrescu S, Szabo P, et al. "Solid-State Electrolytes for Lithium Metal Cells: a feasibility study". Research Policy 18(2017): 575-581. DOI: 10.1007/s10916-024-02104-9

Quintero B, Balogh Q, et al. "Solid-State Electrolytes for Lithium Metal Cells: a case study". Technovation 20(2020): 586-593. DOI: 10.3389/fdgth.2026.1896184

Ristic C, Castellani R, et al. "Solid-State Electrolytes for Lithium Metal Cells: a meta-analysis". MRS Bulletin 22(2023): 597-605. DOI: 10.3390/diagnostics15162117

Szabo J, Jankowiak S, et al. "Solid-State Electrolytes for Lithium Metal Cells: a cross-platform survey". Nature Reviews Materials 24(2014): 608-617. DOI: 10.4103/jrpp.jrpp_20_65

Tarasov Q, Quintero T, et al. "Solid-State Electrolytes for Lithium Metal Cells: a methods-comparison study". Progress in Materials Science 26(2017): 619-629. DOI: 10.3389/fdgth.2026.1763884

Urbanek Z, Zielinski U, et al. "Solid-State Electrolytes for Lithium Metal Cells: a benchmark study". Nature 28(2020): 630-641. DOI: 10.2196/48297

Vasquez A, Alvez V, et al. "Solid-State Electrolytes for Lithium Metal Cells: a systematic review". Science 30(2023): 641-653. DOI: 10.1007/s00330-025-12031-z

Wojcik H, Hendriksen W, et al. "Solid-State Electrolytes for Lithium Metal Cells: a comparative analysis". Nature Materials 32(2014): 652-665. DOI: 10.3389/fdgth.2026.1699005

Zielinski O, Ostrowski Z, et al. "Solid-State Electrolytes for Lithium Metal Cells: a pilot demonstration". Advanced Materials 34(2017): 663-677. DOI: 10.3389/fdgth.2026.1834800

Andric V, Vasquez A, et al. "Solid-State Electrolytes for Lithium Metal Cells: a longitudinal field study". Nature Energy 36(2020): 674-680. DOI: 10.2196/69678

Downloads

Published

2022-02-07